Is available a manual for learning to use ArcGIS 10 (PDF), produced by Amy Hillier at the University of Pennsylvania, includes tips on making maps, georeferencing, modifying attributes, spatial joins, creating spatial data, 3D Analyst and others, before to download you can check the content.
Table of Contents
1| Introduction
Introduction to ArcGIS
Extensions for ArcGIS
Introduction to ArcMap
Managing & Saving Files
Data Formats
2| Spatial Data
Georectifying Images
Working with Projections
3| Making Maps
Symbolizing Points
Symbolizing Polygons
Labeling Features
Designing Map Layouts
Multiple-Map Layouts
Exporting Maps
4| Modifying Attributes
Working with Tables
Calculating Values
Calculating Area, Perimeter & Length
Creating XY Coordinates
Joining Tables
5| Creating & Aggregating
Point
Geocoding
Spatial Joins
6| Querying & Measuring
Querying by Attribute
Querying by Location
Measuring Distances
Buffers
Calculating Distance w/Spatial Joins
Calculating Network Distances
Distance between Matched Pairs
7| Creating New Geographic Files
Editing Shapefiles
Geoprocessing
8| Digitizing
Creating New Shapefiles
Digitizing w/Merge Tool
Creating a Mask
9| Density Maps
10|Working With 3D
3D Analyst
11| Anim ating Tim e Series Data
Animation Toolbar
Tracking Analyst
12| Cartograms
13| Trouble-Shooting